钢结构有机防护涂层结合性能研究进展

王玲玲; 郑国超; 李国强; 杜咏

doi:10.13206/j.gjgS25102901

钢结构有机防护涂层结合性能研究进展

doi: 10.13206/j.gjgS25102901

1. 华侨大学土木工程学院, 福建厦门 361021;
2. 同济大学土木工程学院, 上海 200092;
3. 中国钢结构协会防火与防腐分会, 上海 200092

基金项目:

福建省自然科学基金面上项目（2022J01289）。

详细信息

作者简介:
王玲玲,教授,硕士生导师,主要从事钢结构与结构抗火方向的研究工作。Email:llwang@hqu.edu.cn

计量
- 文章访问数: 6
- HTML全文浏览量: 0
- PDF下载量: 2
- 被引次数: 0
出版历程
- 收稿日期: 2025-10-29

Research Progress on the Bonding Performance of Protective Coatings for Steel Structures

1. College of Civil Engineering, Huaqiao University, Xiamen 361021, China;
2. College of Civil Engineering, Tongji University, Shanghai 200092, China;
3. Fire Protection and Anti-Corrosion Branch, China Steel Structure Association, Shanghai 200092, China

摘要

摘要: 有机涂层作为钢结构防护屏障，其与基材界面的结合性能是决定其防护效能与服役寿命的核心指标之一。该综述阐述了钢结构有机防护涂层结合性能的研究进展，分析了钢结构有机防护涂层结合性能的演化机理和规律；梳理了涂层结合性能的检测方法；阐述了界面内聚力模型的构建与应用。分析表明：目前已揭示了单一因素致变机理，现有界面本构模型聚焦力场作用下界面的损伤断裂行为。未来还需进一步研究多因素耦合作用机制和影响规律，构建考虑多因素耦合（环境条件、火灾高温、应力）作用的界面行为预测模型，为钢结构防护涂层的设计、损伤检测和性能修复提供参考。
- 钢结构防护涂层 /
- 结合性能 /
- 多因素耦合作用 /
- 内聚力模型 /
- 损伤演化 /
- 界面行为
Abstract: For coatings that serve as protective barriers for steel structures， their adhesion strength is a core indicator determining protective efficiency and service life. This paper reviews the research progress on the bonding performance of organic protective coatings for steel structures， analyzes the factors influencing the evolution of bonding performance and their respective mechanisms， summarizes the testing methods for coating bonding performance， and elaborates on the construction and application of interface cohesive models. The analysis shows that the variation mechanisms induced by single factors have currently been revealed， and the existing interface constitutive models focus on the interface damage and fracture behavior under the action of force fields.In the future， it is necessary to further study the coupled action mechanisms and influence patterns of multiple factors， and to construct an interface behavior prediction model that considers the coupling of multiple factors （environmental conditions， fire high temperatures， and stress）， so as to provide references for the design， damage detection， and performance repair of protective coatings for steel structures.
- protective coatings for steel structures /
- bonding performance /
- coupled action of multiple factors /
- cohesive model /
- damage evolution /
- interface behavior

HTML全文

参考文献(59)

[1]	中国金属学会. 2024年我国粗钢产量10.05亿吨,同比降1.7%[EB/OL].(2025-01-20 )[2025-10-29] . https://www.csm.org.cn/col/col6371/art/2025/art_795098885.html.
[2]	王煜成,张逢伯,许清风.锈蚀对既有钢结构性能影响研究进展[J].施工技术,2020,49(9):34-40.
[3]	陈洪亮,王丽晶.大跨度大空间建筑火灾坍塌事故统计分析[J].消防科学与技术,2017,36(4):536-539.
[4]	孙朝,裴彦军,张文学.高铁站房钢结构防护涂层劣化现象及致因分析[J].涂层与防护,2024,45(2):10-16.
[5]	李国强,杜咏.我国建筑钢结构抗火研究与防火技术实践[J].钢结构(中英文),2024,39(10):90-96.
[6]	刘登良.涂层失效分析的方法和工作程序[M].北京:化学工业出版社,2003.
[7]	杨班权,陈光南.涂层与薄膜力学[M].北京:北京理工大学出版社,2020.
[8]	胡传炘,宋幼慧.涂层技术原理及应用[M].北京:化学工业出版社,2000.
[9]	Mariappan T,Kamble A,Naik S M. An investigation of primer adhesion and topcoat compatibility on the waterborne intumescent coating to structural steel[J]. Progress in Organic Coatings,2019,131:371-377.
[10]	Bardal E. Corrosion and protection[M]. London:Springer,2004.
[11]	Knudsen O Ø,Forsgren A. Corrosion control through organic coatings[M]. Boca Roton:CRC Press,2017.
[12]	Leidheiser H Jr.,Wang W,Igetoft L. The mechanism for the cathodic delamination of organic coatings from a metal surface[J]. Progress in Organic Coatings,1983,11(1):19-40.
[13]	Leng A,Streckel H,Stratmann M. The delamination of polymeric coatings from steel. part 1:calibration of the kelvinprobe and basic delamination mechanism[J]. Corrosion Science,1998,41(3):547-578.
[14]	Leng A,Streckel H,Stratmann M. The delamination of polymeric coatings from steel. part 2:first stage of delamination,effect of type and concentration of cations on delamination,chemical analysis of the interface[J]. Corrosion Science,1998,41(3):579-597.
[15]	Leng A,Streckel H,Hofmann K,et al. The delamination of polymeric coatings from steel part 3:effect of the oxygen partial pressure on the delamination reaction and current distribution at the metal/polymer interface[J]. Corrosion Science,1998,41(3):599-620.
[16]	Bi H C,Sykes J. An investigation of cathodic oxygen reduction beneath an intact organic coating on mild steel and its relevance to cathodic disbanding[J]. Progress in Organic Coatings,2015,87:83-87.
[17]	Sørensen P A,Dam-Johansen K,Weinell C E,et al. Cathodic delamination:quantification of ionic transport rates along coating-steel interfaces[J]. Progress in Organic Coatings,2010,67:107-115.
[18]	Sørensen P A,Kiil S,Dam-Johansen K,et al. Anticorrosive coatings:a review[J]. Journal of Coatings Technology and Research,2009,6(2):135-176.
[19]	王军阳,易戈文,万善宏,等。钢材表面氧化铁皮结构演变机理与应用控制技术研究进展[J].中国腐蚀与防护学报,2023,43(5):948-956.
[20]	Zubielewicz M,Królikowska A. The influence of ageing of epoxy coatings on adhesion of polyurethane topcoats and protective properties of coating systems[J]. Progress in Organic Coatings,2009,66(2):129-136.
[21]	Jang I J,Jeon J M,Kim K T,et al. Ultrasonic cavitation behavior and its degradation mechanism of epoxy coatings in 3.5% NaCl at 15℃[J]. Corrosion Science and Technology,2021,20(1):26-36.
[22]	Puspitasari W C,Ahmad F,Ullah S,et al. The study of adhesion between steel substrate,primer,and char of intumescent fire retardant coating[J]. Progress in Organic Coatings,2019,127:181-193.
[23]	刘晓圣,姬军,袁建国,等.膨胀型钢结构防火/防腐涂料体系高温界面结合特性研究[J].涂料工业,2023,53(7):20-26.
[24]	Zhao X,Wang J,Wang Y,et al. Analysis of deterioration process of organic protective coating using EIS assisted by SOM network[J]. Electrochemistry Communications,2007,9:1394-1399.
[25]	Glover C F,Richards C A J,Williams G,et al. Evaluation of multi-layered graphene nano-platelet composite coatings for corrosion control part II-cathodic delamination kinetics[J]. Corrosion Science,2018,136:304-310.
[26]	Song D D,Wan H X,Tu X H,et al. A better understanding of failure process of waterborne coating/metal interface evaluated by electrochemical impedance spectroscopy[J]. Progress in Organic Coatings,2020,142:105558.
[27]	Khayatan N,Rohwerder M. A new insight into the rate determining step of cathodic delamination[J]. Corrosion Science,2022,202:110311.
[28]	Dugdale D S. Yielding of steel sheets containing slits[J]. Journal of the Mechanics and Physics of Solids,1960,8(2):100-104.
[29]	Dadej K,Surowska B. Analysis of cohesive zone model parameters on response of glass-epoxy composite in Mode II interlaminar fracture toughness test[J]. Composites Theory and Practice,2016,16(3):180-188.
[30]	Murer S,Leguillon D. Static and fatigue failure of quasi brittle materials at a V-notch using a Dugdale model[J]. European Journal of Mechanics-A/Solids,2010,29(2):263-278.
[31]	Jang J,Sung M,Han S,et al. Prediction of delamination of steel-polymer composites using cohesive zone model and peeling tests[J]. Composite Structures,2017,160:118-127.
[32]	Chowdhury U,Wu X F. Cohesive zone modeling of the elastoplastic and failure behavior of polymer nanoclay composites[J]. Journal of Composites Science,2021,5(5):131.
[33]	尚一星,尹征南.不同应变率条件下推进剂/衬层界面内聚力模型及其在脱粘模拟中的应用[J/OL].应用力学学报,2025(2025-01-07)[2025 -10-29] . https://link.cnki.net/urlid/61.1112. o3.20250106.1201.020.
[34]	Sun X H,Shi C H,Ge Y Y. Experimental investigation and cohesive zone modelling of the interface mechanical behavior in composite tunnel linings[J]. Tunnelling and Underground Space Technology,2024,150:105837.
[35]	吴业飞,陈伟球.基于内聚力模型的FRP-混凝土粘结强度分析[J].工程力学,2010,27(7):113-119.
[36]	张军.界面应力及内聚力模型在界面力学的应用[M].郑州:郑州大学出版社,2011:5,46,75.
[37]	Chandra N,Li H,Shet C,et al. Some issues in the application of cohesive zone models for metal-ceramic interfaces[J]. International Journal of Solids and Structures,2002,39:2827-2855.
[38]	Volokh K Y. Comparison between cohesive zone models[J]. Communications in Numerical Methods in Engineering,2004,20:845-856.
[39]	Freed Y,Banks-Sills L. A new cohesive zone model for mixed mode interface fracture in bimaterials[J]. Engineering Fracture Mechanics,2008,75:4583-4593.
[40]	Mubashar A,Ashcroft I A,Critchlow G W,et al. Strength prediction of adhesive joints after cyclic moisture conditioning using a cohesive zone model[J]. Engineering Fracture Mechanics,2011,78:2746-2760.
[41]	Özdemir I,Brekelmans W A M,Geers M G D. A thermo-mechanical cohesive zone model[J]. Computational Mechanics,2010,46:735-745.
[42]	Ibrahim G I,Albarbar A. A new approach to the cohesive zone model that includes thermal effects[J]. Composites Part B:Engineering,2019,167:370-376.
[43]	Yang T,Liechti K M,Huang R. A multiscale cohesive zone model for rate-dependent fracture of interfaces[J]. Journal of the Mechanics and Physics of Solids,2020,145:104142.
[44]	Huo X T,Luo Q T,Li Q,et al. On characterization of cohesive zone model (CZM) based upon digital image correlation (DIC) method[J]. International Journal of Mechanical Sciences,2022,215:106921.
[45]	周清春,鞠玉涛,周长省.基于Hooke-Jeeves算法的挠性粘接件的高效内聚反演分析[J].工程力学,2015,32(4):1-7.
[46]	Birro T V,Aufray M,Paroissien E,et al. Assessment of interface failure behaviour for brittle adhesive using the three-point bending test[J]. International Journal of Adhesion and Adhesives,2021,110:102891.
[47]	Volinsky A A,Moody N R,Gerberich W W. Interfacial toughness measurements for thin films on substrates[J]. Actamaterialia,2002,50(3):441-466.
[48]	Cao Q,Oluwoye I,Poojanabuntoeng T,et al. Evaluation of epoxy-based coating degradation under thermal insulation at elevated temperatures on different steel substrates[J]. Progress in Organic Coatings,2023,180:107544.
[49]	Ren F Z,Liu P,Jia S G,et al. Adhesion strength of Ni film on Ti substrate characterized by three-point bend test,peel test and theoretic calculation[J]. Materials Science and Engineering A,2006,419:233-237.
[50]	Potnis P,Holtzinger J,Das D,et al. Study of fracture behaviour of bond coats on nickel superalloy by three-point bending of microbeams[J]. Surface&Coatings Technology,2009,204:586-592.
[51]	Zebar M E M,Hattali M L,Mesrati N. Interfacial fracture toughness measurement in both steady state and transient regimes using four-point bending test[J]. International Journal of Fracture,2020,222:123-135.
[52]	Kim D J,Lee S W,Sung S,et al. Role of loading mode on crack propagation behavior and adhesion at Cu-SiCN interface[J]. Applied Surface Science,2025,688:162461.
[53]	Liang L H,Liu H Y,Long H,et al. Size-dependent damage and fracture of two-layer systems[J]. Engineering Fracture Mechanics,2018,199:635-646.
[54]	Rosa G,Pandora P,Oltra R,et al. Simultaneous laser generation and laser ultrasonic detection of the mechanical breakdown of a coating-substrate interface[J]. Ultrasonics,2001,39:355-365.
[55]	Li Y,Zhu W B,Zou Y. Nondestructive detection of laser-cladding coating interface defects:a deep learning-enhanced laser ultrasonics approach[J]. Nondestructive Testing&Evaluation,2025,40(3):1016-1033.
[56]	Wang H P,Zhang G Q,Li W S,et al. Interface debonding defect detection of thermal barrier coatings with laser lock-in thermography based on edge sharpness optimization[J]. Infrared Physics&Technology,2025,146:105744.
[57]	张中浩,梅红伟,刘建军,等.基于太赫兹波的复合绝缘子界面检测研究[J].中国电机工程学报,2020,40(3):989-998.
[58]	丁俊才,吴斌,何存富,等.黏接结构中超声波的能量反射与透射特性[J].北京工业大学学报,2016,42(3):329-337.
[59]	Sma I,Ünaldı S,Ayad M,et al. Laser shock adhesion testing of thermally aged epoxy coatings[J]. Progress in Organic Coatings,2024,195:108603.