多元微合金化耐火钢研究进展

王鑫; 李昭东; 张可; 王文涛; 杨忠民; 雍岐龙

doi:10.13206/j.gjgS20073101

多元微合金化耐火钢研究进展

doi: 10.13206/j.gjgS20073101

王鑫^1,2,
李昭东^1, ,,
张可³,
王文涛^1,3,
杨忠民¹,
雍岐龙¹

1. 钢铁研究总院工程用钢研究所, 北京 100081;
2. 北京科技大学钢铁共性技术协同创新中心, 北京 100083;
3. 安徽工业大学冶金工程学院, 安徽马鞍山 243032

基金项目:

国家重点研发计划（2017YFB0304700，2017YFB0304702）；国家自然科学基金项目（51704008）。

详细信息

作者简介:
王鑫,男,1988年出生,博士。

通讯作者:
李昭东,男,1983年出生,博士,高级工程师,cisri_lizhaodong@126.com。

计量
- 文章访问数: 267
- HTML全文浏览量: 48
- PDF下载量: 17
- 被引次数: 0
出版历程
- 收稿日期: 2020-07-31
- 网络出版日期: 2021-06-17

Research Progress on Multi-Microalloyed Fire-Resistant Steel

1. Department of Structural Steels, Central Iron and Steel Research Institute, Beijing 100081, China;
2. Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China;
3. School of Metallurgical Engineering, Anhui University of Technology, Maanshan 243032, China

摘要

摘要: 随着社会经济的不断发展，建筑行业对于建筑材料强度的要求也越来越高，建筑结构用钢的组织类型也由铁素体/珠光体向铁素体/贝氏体、全贝氏体和多相多尺度亚稳（M³）组织方向发展。耐火钢以其优异的综合性能和良好的耐火安全性等优点，被广泛应用于高层及大跨度建筑中。对于耐火性能的调控方式也从高成本的高Mo （≥0.40%）加单一元素的微合金化为主的方式向经济型的节Mo （≤0.30%）加Nb、V和Ti等多元复合微合金化方式发展。详细介绍了国内外耐火钢的发展历史、产品种类和应用工程以及提高耐火钢室温强度和耐火性能的理论和技术，对比研究了不同组织和微合金元素的耐火性能的差异。研究表明，多元复合微合金化钢在室温和600℃高温的性能要优于单一元素的微合金化钢的性能，因此提出了多元复合微合金纳米碳化物遇火析出增强高温耐火性能的新思路。针对Q345~Q690不同强度级别耐火钢，形成了差异化的合金与组织设计及其热轧/热处理技术，利用扫描电镜（SEM）观察不同强度级别耐火钢的组织类型，阐明了典型多元复合微合金化耐火钢升温-加载过程中显微组织和力学性能的变化规律。采用透射电镜（TEM）、物理化学相分析和三维原子探针（3DAP）等研究方法观察和统计热轧态、不同热处理态和600℃高温拉伸态析出相的分布、尺寸和数量，探讨了纳米碳化物高温沉淀强化、基体组织高温稳定的耐火机理。研究表明，经过弛豫处理的Q345级别钢板为先共析铁素体+少量贝氏体/珠光体组织，具有较高的细晶和沉淀强化增量；轧后直接进行层流冷却的Q345级别钢板为全贝氏体组织，有着较高的位错和固溶强化增量，600℃拉伸的屈服强度（Yield Strength，YS）仍能达到327 MPa。Q460级别钢板为全贝氏体组织，600℃时组织具有良好的高温稳定性，随着在600℃时保温时间的延长，直径小于10 nm的纳米析出相显著增加。Q690级别钢板为马氏体+亚稳奥氏体+纳米析出相和低碳高强贝氏体组织，室温下具有690 MPa的屈服强度和良好的延伸性能，经600℃高温拉伸试验后，其屈服强度不低于室温标准屈服强度的2/3。采用多元微合金化设计、遇火纳米析出强化的调控思路可实现Q345~Q690不同级别耐火钢的耐火功能。
- 微合金化 /
- 耐火钢 /
- 纳米析出 /
- 耐火机制
Abstract: With the development of social economy, the construction industry has put forward higher requirements for the strength of building materials. The microstructure of construction steel for building has developed from ferrite/pearlite to ferrite/bainite, bainite, multiphase and multiscale metastable (M³). Fire-resistant steel is widely used in high-rise and large-span buildings due to its excellent comprehensive properties and good fire resistant safety. The control of fire resistance properties has also evolved from high-cost high Mo (≥0. 40%) plus single microalloyed mode to economical saving Mo (≤ 0. 30%) plus Nb, V and Ti and other composite multimicroalloyed methods. The development history, product types and application engineering of fire resistance steel at home and abroad, as well as theories and technologies to improve the strength and fire resistance of fire-resistance steel were introduced in detail. The differences in the fire resistance properties of different microstructures and microalloy elements were comparatively studied. The research shows that the room temperature and 600 ℃ properties of the composite multi-microalloyed steel are better than that of the single microalloyed steel, and puts forward a new idea of multi-microalloyed nano-carbide precipitated in fire to enhance the fire resistance properties. For Q345-Q690 fire-resistance steel, the differentiated alloy and microstructure design and its hot rolling/heat treatment technology were formed. The microstructure types of different strength grades of fire-resistance steels were observed by scanning electron microscopy (SEM), and the microstructure and mechanical properties of typical multi-microalloyed fire-resistance steel during reheating-loading process were clarified. The distribution, size and quantity of precipitated phases in hot-rolled state, heat-treated state and 600 ℃ tensile state were observed and counted by transmission electron microscopy (TEM), physical and chemical phase analysis and three-dimensional atom probe (3DAP). The fire resistance mechanism of nano-carbide precipitation strengthening and matrix microstructure stability in high temperature were discussed. The study shows the Q345 grade steel plate after relaxation treatment is proeutectoid ferrite and a small amount of bainite/pearlite microstructure, with high fine grain and precipitation strengthening increments, and the Q345 grade steel plate directly subjected to laminar cooling after rolling is full bainite microstructure with high dislocations and solid solution strengthening increments, its yield strength at 600 ℃ can still reach 327 MPa. The Q460 grade steel plate is bainite microstructure, and the microstructure has good high temperature stability at 600 ℃. With the extension of the holding time at 600 ℃, the nano-precipitated phases that a diameter is less than 10 nm increases significantly. Q690 grade steel plate is martensite, metastable austenite and nano-precipitated phase and low carbon high strength bainite microstructure. It has a yield strength of 690 MPa and good elongation at room temperature. After 600 ℃ tensile test, its yield strength is not lower than 2/3 of the standard yield strength at room temperature. The control idea of multi-microalloyed design and nano-precipitation strengthening in fire can realize the fire resistant property of different grades of Q345-Q690 fire-resistant steel.
- microalloyed /
- fire-resistant steel /
- nano-precipitation /
- fire resistant mechanism

HTML全文

参考文献(41)

李久清.钢结构的应用现状及发展前途[J].内蒙古科技与经济,2005(20):76-77.

刘志勇,杨才福,沈俊昶,等.建筑用耐火钢组织与性能的研究[J].钢结构,2005,20(4):75-79.

杨才福,张永权.建筑用耐火钢的发展[J].钢结构,1997,12(4):29-34.

沈俊昶,刘志勇,杨才福,等.建筑用耐火钢的高温强化机理[J].钢铁研究学报,2007(4):75-79.

Bennetts I D,Moinuddin K A M,Goh C C,et al.Testing and factors relevant to the evaluation of the structural adequacy of steel members within fire-resistant elevator shafts[J].Fire Safety Journal,2005,40(8):698-727.

陈晓,刘继雄,董汉雄,等.高性能耐火耐候建筑用钢的高温性能及耐火性能[J].中国有色金属学报,2004(增刊1):231-236.

沈俊昶,杨才福,马鸣图,等.耐火钢综合性能及构件抗火试验分析[J].钢结构,2006,21(4):87-91.

张正延.高Nb低碳钢中Mo对纳米级析出相及组织性能的影响研究[D].沈阳:东北大学,2015.

刘志勇.建筑用耐火钢性能与组织的研究[D].昆明:昆明理工大学,2005.

郭瑞璜,作本好文.日本研制应用耐火钢的概况[J].消防技术与产品信息,2012(11):87-89.

Assefpour-Dezfuly M,Hugaas B A,Brownrigg A.Fire resistant high strength low alloy steels[J].Materials and Science and Technology,1999,6(12):1210-1214.

Ruth E W.Metals handbook[M].Metals Park:American Society for Metals,1990:17.

Robinson J.Fire:a technical challenge and a market opportunity[J].Journal of Constructional Steel Research,1998,46(1/2/3):307.

Bakkaloglu A.Effect of processing parameters on the microstructure and properties of an Nb microalloyed steel[J].Materials Letters,2002,56(3):263-272.

刘志勇,杨才福,张永权,等.建筑用耐火H型钢性能与组织的研究[J].金属热处理,2005(6):45-50.

Uemori R,Tamehiro H,Chijiiwa R.AP-FIM analysis of ultrafine carbonitrides in fire-resistant steel for building construction[J].Nippon Steel Technical Report,1996(69):23-28.

Sellars C M.The technology and properties of ferrous alloys for high temperature use[J].The Aeronautical Journal,1967,71(678):242-441.

Chang S K,Kwak J H.Effect of manganese on aging in low carbon sheet steels[J].ISIJ International,1997,37(1):74-79.

吴保桥,吴结才,沈俊昶,等.建筑用耐火H型钢的开发[J].轧钢,2004(2):13-15.

王泽林.高层建筑用耐火钢的研制[J].鞍钢技术,2004(2):23-27.

陈晓,刘继雄,董汉雄,等.大线能量焊接耐火耐候建筑用钢的研制及应用[J].中国有色金属学报,2004(增刊1):224-230.

陈晓,郭爱民,董汉雄,等.高性能耐火耐候建筑用钢及其生产方法[J].武钢技术,2008(4):54.

刘继雄,李平和,王玉涛,等.高性能耐火耐候建筑用钢自动埋弧焊焊评试验中的裂纹分析[J].焊接学报,2003(6):89-93.

王泽林,王道远,张智义,等.耐火钢及其制造方法:CN1524976[P].2004-09-01.

孙建国,吴子良.对新钢种耐候钢及耐火钢力学性能的探讨[J].莱钢科技,2002(6):46-47.

段小雪,李龙,丁桦,等.建筑用耐火钢控轧控冷实验研究[J].塑性工程学报,2003(5):93-96.

韦明,李玉谦.舞钢高层建筑结构用钢板的开发[J].钢结构,2004,19(4):59-61.

尹人洁,王婀娜,藤建明,等.一种耐火钢、耐火无缝钢管及其生产方法:CN101285153[P].2008-10-15.

Lee W B,Hong S G.Carbide precipitation and high-temperature strength of hot-rolled high-strength low-alloy steels containing Nb and Mo[J].Meallurgical and Materials Transactions,2002,33:1689-1698.

Chijiiwa R,Tamehiro H,Yoshida Y,et al.Development and practical application of fire-resistant steel for buildings[J].Nippon Steel Technical Report,1993,58:48-55.

Speer J G,Jansto S G,Cross J C,et al.Elevated temperature properties of niobium microalloyed steels for fire-resistant structural applications[C]//Proceedings of the Joint International Conference of HSLA Steels 2005 and ISUGS 2005.Beijing:2005:818-823.

Sha W,Kelly F S,Guo Z X.Microstructure and properties of Nippon fire-resistant steels[J].Materials Engineering and Performance,1999,8(5):606-612.

Sha W,Kirby B R,Kelly F S.The behavior of structural steels at elevated temperatures and the design of fire resistant steels[J].Materials Transactions,2001,42(9):1913-1927.

潘小强.合金元素Mo-V对耐火钢组织及性能的影响[D].重庆:重庆大学,2007.

党莹.低钼建筑用耐火钢组织和性能的研究[D].重庆:重庆大学,2007.

雍岐龙.钢铁材料中的第二相[M].北京:冶金工业出版社,2006.

董瀚.现进钢铁材料[M].北京:科学出版社,2007.

Cao Y B,Xiao F R,Qiao G Y,et al.Strain-induced precipitation and softening behaviors of high Nb microalloyed steels[J].Materials Science and Engineering:A,2012,552:502-513.

Zhang Z Y,Sun X J,Li Z D,et al.Effect of nanometer-sized carbides and grain boundary density on performance of Fe-C-Mo-M (M=Nb,V or Ti) fire resistant steels[J].Chinese Journal of Materials Research,2015,29(4):269-276.

Yang G W,Sun X J,Li Z D,et al.Effects of vanadium on the microstructure and mechanical properties of a high strength low alloy martensite steel[J].Materials and Design,2013,50:102-107.

Lee C G,Kim S J,Lee T H,et al.Effects of volume fraction and stability of retained austenite on formability in a 0.1C-1.5Si-1.5Mn-0.5Cu TRIP-aided cold-rolled steel sheet[J].Materials Science and Engineering:A,2004,371(1):16-23.

施引文献

资源附件(0)

访问统计